(2,4,6-Trinitrophenyl)guanidine
| File | Size | Format | |
|---|---|---|---|
| 49946_1.pdf | 1946Kb | Adobe PDF | View |
| Title | (2,4,6-Trinitrophenyl)guanidine |
|---|---|
| Author | Smith, Graham; Wermuth, Urs; White, Jonathan M. |
| Journal Name | Acta Crystallographica Section E, Structure Reports Online |
| Year Published | 2007 |
| Place of publication | Copenhagen, Denmark |
| Publisher | Blackwell Munksgaard |
| Abstract | (2,4,6-Trinitrophenyl)guanidine (picrylguanidine), C7H6N6O6, from the reaction of picrylsulfonic acid with guanidine carbonate, forms a three-dimensional framework structure through extensive hydrogen-bonding interactions, extending the centrosymmetric cyclic R22(16) dimer association which includes duplex R22(8) guanidine N—H...Onitro interactions. The guanidine substituent chain has an endo [Ph—N=C(NH2)2] bond sequence rather than the less sterically encumbered exo [Ph—NH—C=NH(NH2)] sequence of the tautomeric form. As a result, there is significant bond-angle distortion about C(—N=) of the aromatic ring. |
| Peer Reviewed | Yes |
| Published | Yes |
| Publisher URI | http://www3.interscience.wiley.com/journal/118529086/abstract |
| Alternative URI | http://dx.doi.org/10.1107/S1600536807038068 |
| Copyright Statement | Copyright remains with the authors 2007. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode |
| Volume | E63 |
| Issue Number | 9 |
| Page from | O3759 |
| Page to | O3759 |
| ISSN | 1600-5368 |
| Date Accessioned | 2008-03-26 |
| Date Available | 2009-09-24T05:51:54Z |
| Language | en_AU |
| Faculty | Faculty of Science, Environment, Engineering and Technology |
| Subject | PRE2009-Structural Chemistry |
| URI | http://hdl.handle.net/10072/17598 |
| Publication Type | Journal Articles (Refereed Article) |
| Publication Type Code | c1 |
Please use this identifier to cite this record: http://hdl.handle.net/10072/17598
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