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Title (2,4,6-Trinitrophenyl)guanidine
Author Smith, Graham; Wermuth, Urs; White, Jonathan M.
Journal Name Acta Crystallographica Section E, Structure Reports Online
Year Published 2007
Place of publication Copenhagen, Denmark
Publisher Blackwell Munksgaard
Abstract (2,4,6-Trinitrophenyl)guanidine (picrylguanidine), C7H6N6O6, from the reaction of picrylsulfonic acid with guanidine carbonate, forms a three-dimensional framework structure through extensive hydrogen-bonding interactions, extending the centrosymmetric cyclic R22(16) dimer association which includes duplex R22(8) guanidine N—H...Onitro interactions. The guanidine substituent chain has an endo [Ph—N=C(NH2)2] bond sequence rather than the less sterically encumbered exo [Ph—NH—C=NH(NH2)] sequence of the tautomeric form. As a result, there is significant bond-angle distortion about C(—N=) of the aromatic ring.
Peer Reviewed Yes
Published Yes
Publisher URI http://www3.interscience.wiley.com/journal/118529086/abstract
Alternative URI http://dx.doi.org/10.1107/S1600536807038068
Copyright Statement Copyright remains with the authors 2007. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Volume E63
Issue Number 9
Page from O3759
Page to O3759
ISSN 1600-5368
Date Accessioned 2008-03-26
Language en_AU
Faculty Faculty of Science, Environment, Engineering and Technology
Subject PRE2009-Structural Chemistry
URI http://hdl.handle.net/10072/17598
Publication Type Journal Articles (Refereed Article)
Publication Type Code c1

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