4-Chloroanilinium hydrogen (2R,3R)-tartrate monohydrate
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Author(s)
Smith, Graham
Wermuth, Urs D
White, Jonathan M
Griffith University Author(s)
Year published
2007
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Show full item recordAbstract
In the structure of the hydrated 1:1 compound of 4-chloroaniline with L-tartaric acid, C6H7ClN+烴H5O6-爲O, determined at 130 K, the asymmetric unit comprises two 4-chloroanilinium cations, two hydrogen tartrate anions and two water molecules of solvation, and forms a two-dimensional duplex substructure comprising head-to-tail C11(7) hydrogen-bonded hydrogen tartrate anions and water molecules. The [pi]-associated 4-chloroanilinium cation pairs [ring centroid separation = 3.576 (4) Ż inter-ring dihedral angle = 0.5 (1)ݠare accommodated within the channels of the substructure and are hydrogen-bonded to it peripherally.In the structure of the hydrated 1:1 compound of 4-chloroaniline with L-tartaric acid, C6H7ClN+烴H5O6-爲O, determined at 130 K, the asymmetric unit comprises two 4-chloroanilinium cations, two hydrogen tartrate anions and two water molecules of solvation, and forms a two-dimensional duplex substructure comprising head-to-tail C11(7) hydrogen-bonded hydrogen tartrate anions and water molecules. The [pi]-associated 4-chloroanilinium cation pairs [ring centroid separation = 3.576 (4) Ż inter-ring dihedral angle = 0.5 (1)ݠare accommodated within the channels of the substructure and are hydrogen-bonded to it peripherally.
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Journal Title
Acta Crystallographica Section E, Structure Reports Online
Volume
E63
Issue
8
Publisher URI
Copyright Statement
© The Author(s) 2007. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Subject
Chemical sciences