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dc.contributor.authorSmith, Graham
dc.contributor.authorWermuth, Urs D
dc.contributor.authorWhite, Jonathan M
dc.contributor.editorGeorge Ferguson
dc.date.accessioned2017-05-03T11:22:53Z
dc.date.available2017-05-03T11:22:53Z
dc.date.issued2007
dc.date.modified2009-09-24T05:53:48Z
dc.identifier.issn0108-2701
dc.identifier.doi10.1107/S0108270107032295
dc.identifier.urihttp://hdl.handle.net/10072/17600
dc.description.abstractThe structure of a third pseudopolymorphic hydrate of brucine, brucine-water (1/2) [systematic name: 2,3-dimethoxystrychnidin-10-one-water (1/2)], C23H26N2O4粈2O, has been determined at 130 K. The asymmetric unit comprises two independent brucine molecules and four water molecules of solvation. The four water molecules form uncommon cyclic hydrogen-bonded homomolecular R44(8) tetramer rings, which then form primary hydrogen-bonded chain substructures extending down the 21 screw axis in the unit cell. The two brucine molecules are linked peripherally to these substructures by either single O-H...Nbrucine or asymmetric three-centre O-H...Obrucine hydrogen bonds.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherBlackwell Munksgaard
dc.publisher.placeCopenhagen, Denmark
dc.publisher.urihttps://onlinelibrary.wiley.com/iucr/doi/10.1107/S0108270107032295
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefromO489
dc.relation.ispartofpagetoO492
dc.relation.ispartofissue8
dc.relation.ispartofjournalActa Crystallographica Section C, Crystal Structure Communications
dc.relation.ispartofvolumeC63
dc.rights.retentionY
dc.subject.fieldofresearchInorganic chemistry
dc.subject.fieldofresearchPhysical chemistry
dc.subject.fieldofresearchOther chemical sciences
dc.subject.fieldofresearchcode3402
dc.subject.fieldofresearchcode3406
dc.subject.fieldofresearchcode3499
dc.titlePseudopolymorphism in brucine: brucine-water (1/2), the third crystal hydrate of brucine
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2007
gro.hasfulltextNo Full Text
gro.griffith.authorWermuth, Urs D.


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