dc.contributor.author | Smith, Graham | |
dc.contributor.author | Wermuth, Urs D | |
dc.contributor.author | White, Jonathan M | |
dc.contributor.editor | George Ferguson | |
dc.date.accessioned | 2017-05-03T11:22:53Z | |
dc.date.available | 2017-05-03T11:22:53Z | |
dc.date.issued | 2007 | |
dc.date.modified | 2009-09-24T05:53:48Z | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.doi | 10.1107/S0108270107032295 | |
dc.identifier.uri | http://hdl.handle.net/10072/17600 | |
dc.description.abstract | The structure of a third pseudopolymorphic hydrate of brucine, brucine-water (1/2) [systematic name: 2,3-dimethoxystrychnidin-10-one-water (1/2)], C23H26N2O4粈2O, has been determined at 130 K. The asymmetric unit comprises two independent brucine molecules and four water molecules of solvation. The four water molecules form uncommon cyclic hydrogen-bonded homomolecular R44(8) tetramer rings, which then form primary hydrogen-bonded chain substructures extending down the 21 screw axis in the unit cell. The two brucine molecules are linked peripherally to these substructures by either single O-H...Nbrucine or asymmetric three-centre O-H...Obrucine hydrogen bonds. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Blackwell Munksgaard | |
dc.publisher.place | Copenhagen, Denmark | |
dc.publisher.uri | https://onlinelibrary.wiley.com/iucr/doi/10.1107/S0108270107032295 | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | O489 | |
dc.relation.ispartofpageto | O492 | |
dc.relation.ispartofissue | 8 | |
dc.relation.ispartofjournal | Acta Crystallographica Section C, Crystal Structure Communications | |
dc.relation.ispartofvolume | C63 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Inorganic chemistry | |
dc.subject.fieldofresearch | Physical chemistry | |
dc.subject.fieldofresearch | Other chemical sciences | |
dc.subject.fieldofresearchcode | 3402 | |
dc.subject.fieldofresearchcode | 3406 | |
dc.subject.fieldofresearchcode | 3499 | |
dc.title | Pseudopolymorphism in brucine: brucine-water (1/2), the third crystal hydrate of brucine | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2007 | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Wermuth, Urs D. | |