Selective Monoesterification of Malonic Acid Catalyzed by Boric Acid
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| Title | Selective Monoesterification of Malonic Acid Catalyzed by Boric Acid |
|---|---|
| Author | Levonis, Stephan; Bornaghi, Laurent; Houston, Todd Ashley |
| Journal Name | Australian Journal of Chemistry |
| Year Published | 2007 |
| Place of publication | Australia |
| Publisher | CSIRO Publishing |
| Abstract | Boric acid catalyzes the monoesterification of malonic acid, likely through a chelation mechanism that is not available to the monoester product. Under more forcing conditions, diesters form to some extent, but conditions can be optimized to favour the monoester product (56–80%). With the easily handled solid acid catalyst, these reactions can be run with excess alcohol as solvent or with stoichiometric amounts of alcohol in acetonitrile with moderate heating. |
| Peer Reviewed | Yes |
| Published | Yes |
| Publisher URI | http://www.publish.csiro.au/journals/ajc |
| Alternative URI | http://dx.doi.org/10.1071/CH07231 |
| Volume | 60 |
| Page from | 821 |
| Page to | 823 |
| ISSN | 0004-9425 |
| Date Accessioned | 2008-02-29 |
| Date Available | 2009-12-02T05:54:51Z |
| Language | en_AU |
| Research Centre | Institute for Glycomics |
| Faculty | Faculty of Science, Environment, Engineering and Technology |
| Subject | PRE2009-Organic Chemical Synthesis |
| URI | http://hdl.handle.net/10072/17937 |
| Publication Type | Journal Articles (Refereed Article) |
| Publication Type Code | c1 |
Please use this identifier to cite this record: http://hdl.handle.net/10072/17937
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