The v2 vibration of the carbonate species

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Title The v2 vibration of the carbonate species
Author Healy, Peter Conrad; White, A. H.
Journal Name Spectrochimica Acta Part A: Molecular Spectroscopy
Year Published 1973
Place of publication Netherlands
Publisher Pergamon Press
Abstract The frequency of the V2i.r. active out-of-plane mode of the planar carbonate species in complexes of known crystal structure in a variety of coordination and site symmetry types varies between 820 and 880 cm−1. Within the context of the observed geometries and frequencies and an analysis of the motion of the CO3 system normal to the CO3 plane, the frequency is found to depend only on the variation in the force constant, the kinetic energy term being invariant. A tentative correlation with possible diagnostic applications is drawn between the ν2 frequency and site symmetry/coordination type.
Peer Reviewed Yes
Published Yes
Alternative URI http://dx.doi.org/10.1016/0584-8539(73)80156-4
Volume 29A
Page from 1191
Page to 1195
ISSN 0584-8539
Date Accessioned 2007-11-15
Date Available 2015-05-15T04:40:29Z
Language en_US
Faculty Faculty of Science, Environment, Engineering and Technology
Subject PRE2009-Chemical Spectroscopy
URI http://hdl.handle.net/10072/19638
Publication Type Journal Articles (Refereed Article)
Publication Type Code c1x

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