dc.contributor.author | HEALY, PC | |
dc.contributor.author | PATRICK, JM | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:09:26Z | |
dc.date.available | 2017-05-03T11:09:26Z | |
dc.date.issued | 1984 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9841105 | |
dc.identifier.uri | http://hdl.handle.net/10072/25009 | |
dc.description.abstract | The crystal structure of the title complex, [H3NCH2CH2NH3] [Ni(H2O)6] [SO4]2, has been determined by single-crystal X-ray diffraction methods at 295 K, being refined by full matrix least squares to a residual of 0.032 for 2532 independent 'observed' reflections. Crystals are monoclinic, P21/n, a 13.148(3), b 7.119(3), c 8.245(2) Ŭ ߠ100.97(4)ꬠZ = 2. Both cations are disposed about crystallographic centres of symmetry. The organic species has a necessarily planar non-hydrogen atom skeleton [C-C, 1.513(3); C-N, 1.485(4) ŝ. In the hexaaquanickel(11) species, the Ni-O distances are very similar [2.060(2), 2.064(2), 2.066(2) ŝ, although there is a significant departure from octahedral symmetry among the angles [89.71(8), 86.87(8), 90.00(8)Ꝯ The oxygen atoms of the water molecules are bonded pseudo-tetrahedrally. The centrosymmetric metal atom environment is more regular than that in the corresponding Tutton salts, to which complexes of the present type may present an attractive alternative. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Australia | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 1105 | |
dc.relation.ispartofpageto | 1109 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 37 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Crystal structure of ethylenediammonium hexaaquanickel(II) sulphate: a variation on the Tutton salts | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:27:38Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |