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dc.contributor.authorHEALY, PC
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:29Z
dc.date.available2017-05-03T11:09:29Z
dc.date.issued1983
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9832057
dc.identifier.urihttp://hdl.handle.net/10072/25011
dc.description.abstractThe crystal structure of [Fe(bpy)3] [CI3FeOFeCI3] (1) has been determined by single-crystal X-ray diffraction at 295 K, and refined by least squares to a residual of 0.058 for 2002 'observed' reflections. Crystals are monoclinic, P21/c, a 9.616(3), b 26.264(6), c 13.821(7) ?, ߠ99.68(2)ଠZ4. In the cation, Fe-N distances range from 1.956(9) to 1 .989(10) ?; in the anion, Fe-Cl distances range from 2.196(5) to 2.225(5) ?. Fe-O distances are 1.763(11) and 1.740(11) ?, and the Fe-O-Fe angle is 148.9(7)஠Recrystallization of 'compound A' from methanolic aqueous solution yields crystals with stoichiometry [{cis-Fe(phen)2Cl}2O]Cl2.nH2O( n 蠴.5) as established by structure determination (hampered by serious disorder); R is 0.09 for 749 'observed' reflections. Crystals are orthorhombic, Pcn2, a 18.05(1), b 13.83(1), c 10.481(6) ?, Z 2. The Fe-N distances trans to each other are 2.12(3) and 2.13(3) ?; Fe-N distances trans to Cl and O are 2.20(2) and 2.28(2) ?, respectively. Fe-CI is 2.34(1) and Fe-O 1.787(6) A; Fe-O-Fe is 161(1)஠For crystals from aqueous solution, an isomorphous but larger unit cell is obtained [2754(7), cf. 2616(3) ?3]; it is believed that this is a consequence of variable occupancy of the disordered solvent layers which lie parallel to bc between the ionic species.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom2057
dc.relation.ispartofpageto2064
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume36
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleStructural studies in the iron(III)/chloride/α,α'-diimine system. III : Crystal structures of tris(2,2'-bipyridine)iron(II) µ-Oxo-bis[trichloroferrate(III)] and of 'compound A', µ-Oxo-bis[cis-chlorobis-(1,10-phenanthroline)iron(III)] chloride solvate
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:28:21Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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