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dc.contributor.authorHARDIN, SG
dc.contributor.authorHEALY, PC
dc.contributor.authorMUMME, WG
dc.contributor.authorWHITE, AH
dc.contributor.authorWINTER, G
dc.date.accessioned2017-05-03T11:09:31Z
dc.date.available2017-05-03T11:09:31Z
dc.date.issued1982
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9822423
dc.identifier.urihttp://hdl.handle.net/10072/25033
dc.description.abstractThe crystal structures of the title compounds have been carried out by single-crystal X-ray diffraction methods at 295 K. For (1), [(EtOCS2)Pb(C9H6NO)2Pb(S2COEt)], crystals are triclinic, P1, a 11.600(6), b 8.9739, c 6.863(4) Ŭ a 96.79(5), ߠ90.19(5), ? 101.54(4)ꬠwith one dimer in the cell. R was 0.038 for 3109 'observed' reflections. The lead atom is coordinated by two sulfur atoms from the xanthate ligand [Pb-S 2.705(3), 3.173(3) ŝ, the quinolin-8-olato nitrogen atom [Pb-N 2.479(6) ŝ and the oxygen atom which bridges two centrosymmetrically related lead atoms [Pb-O 2.296(5), 2.548(4) ŝ. For (2), (Et4N) [Pb(S2COEt)3], crystals are monoclinic, P21/c, a 10.827(3), b 18.889(6), c 14.292(5) Ŭ ߠ111.05(2)ꬠZ 4. R was 0.050 for 3657 'observed' reflections. The lead atom is surrounded by the six sulfur atoms [Pb-S 2.754(4)-3.126(3) ŝ, with close approaches from the two sulfur atoms of one of the ligands of a centrosymmetrically related anion [Pb.. .S 3.545(4), 3.555(4) ŝ, in a similar manner to that observed in the 'isoelectronic' tris(N,N-diethyldithiocarbamato)bismuth(III) complex.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom2423
dc.relation.ispartofpageto2433
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume35
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleCrystal structures of dimeric O-ethylxanthato-quinolin-8-olato-lead(II) and of tetraethylammonium tris(O-ethylxanthato)plumbate(II)
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:28:40Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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