dc.contributor.author | HARDIN, SG | |
dc.contributor.author | HEALY, PC | |
dc.contributor.author | MUMME, WG | |
dc.contributor.author | WHITE, AH | |
dc.contributor.author | WINTER, G | |
dc.date.accessioned | 2017-05-03T11:09:31Z | |
dc.date.available | 2017-05-03T11:09:31Z | |
dc.date.issued | 1982 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9822423 | |
dc.identifier.uri | http://hdl.handle.net/10072/25033 | |
dc.description.abstract | The crystal structures of the title compounds have been carried out by single-crystal X-ray diffraction methods at 295 K. For (1), [(EtOCS2)Pb(C9H6NO)2Pb(S2COEt)], crystals are triclinic, P1, a 11.600(6), b 8.9739, c 6.863(4) Ŭ a 96.79(5), ߠ90.19(5), ? 101.54(4)ꬠwith one dimer in the cell. R was 0.038 for 3109 'observed' reflections. The lead atom is coordinated by two sulfur atoms from the xanthate ligand [Pb-S 2.705(3), 3.173(3) ŝ, the quinolin-8-olato nitrogen atom [Pb-N 2.479(6) ŝ and the oxygen atom which bridges two centrosymmetrically related lead atoms [Pb-O 2.296(5), 2.548(4) ŝ. For (2), (Et4N) [Pb(S2COEt)3], crystals are monoclinic, P21/c, a 10.827(3), b 18.889(6), c 14.292(5) Ŭ ߠ111.05(2)ꬠZ 4. R was 0.050 for 3657 'observed' reflections. The lead atom is surrounded by the six sulfur atoms [Pb-S 2.754(4)-3.126(3) ŝ, with close approaches from the two sulfur atoms of one of the ligands of a centrosymmetrically related anion [Pb.. .S 3.545(4), 3.555(4) ŝ, in a similar manner to that observed in the 'isoelectronic' tris(N,N-diethyldithiocarbamato)bismuth(III) complex. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Australia | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 2423 | |
dc.relation.ispartofpageto | 2433 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 35 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Crystal structures of dimeric O-ethylxanthato-quinolin-8-olato-lead(II) and of tetraethylammonium tris(O-ethylxanthato)plumbate(II) | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:28:40Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |