Radical Carboxyarylation Approach to Lignans. Total Synthesis of (−)-Arctigenin, (−)-Matairesinol, and Related Natural Products

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Title Radical Carboxyarylation Approach to Lignans. Total Synthesis of (−)-Arctigenin, (−)-Matairesinol, and Related Natural Products
Author Fischer, Joshua; Reynolds, Aaron J.; Sharp, Lisa A.; Sherburn, Michael S.
Journal Name Organic Letters
Editor Amos B Smith, Carol Carr
Year Published 2004
Place of publication United States
Publisher American Chemical Society
Abstract Total syntheses of seven biologically important lignan natural products, including (−)-arctigenin, (−)-matairesinol, and (−)-α-conidendrin, by way of a highly stereoselective domino radical sequence is presented. The reported stereochemistry of the natural product 7-hydroxyarctigenin is shown to be erroneous; a diastereoisomeric structure is assigned to the natural product.
Peer Reviewed Yes
Published Yes
Alternative URI http://dx.doi.org/10.1021/ol049878b
Volume 6
Issue Number 9
Page from 1345
Page to 1348
ISSN 1523-7060
Date Accessioned 2009-08-18
Date Available 2009-08-25T03:45:56Z
Language en_AU
Faculty Faculty of Science, Environment, Engineering and Technology
Subject PRE2009-Organic Chemical Synthesis
URI http://hdl.handle.net/10072/25281
Publication Type Journal Articles (Refereed Article)
Publication Type Code c1x

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