A one-pot synthesis of novel N,N-dialkyl-S-glycosylsulfenamides

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Title A one-pot synthesis of novel N,N-dialkyl-S-glycosylsulfenamides
Author von Itzstein, Mark; Owen, David J.
Journal Name Carbohydrate Research
Year Published 2000
Place of publication UK
Publisher Pergamon
Abstract An efficient new entry into N,N-dialkyl-S-glycosylsulfenamides is reported. The reaction of bis-activated alkyl halides in the presence of a secondary amine base with glycosylic S-acetyl derivatives (1-S-acetyl-1-thioaldoses or 2-S-acetyl-2-thioketoses) results in the formation of novel carbohydrate sulfenamides. These new carbohydrate-based sulfenamides may provide useful derivatives with biological activity, as well as provide reactive carbohydrate sulfenylating agents.
Peer Reviewed Yes
Published Yes
Publisher URI http://www.elsevier.com/wps/find/journaldescription.cws_home/424829/description#description
Copyright Statement Copyright 2000 Elsevier : Reproduced in accordance with the copyright policy of the publisher : This journal is available online - use hypertext links.
Volume 328
Page from 287
Page to 292
ISSN 0008-6215
Date Accessioned 2001-01-01
Language en_AU
Research Centre Institute for Glycomics
Subject Science & Technology
URI http://hdl.handle.net/10072/2982
Publication Type Article in Scholarly Refereed Journal
Publication Type Code c1

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