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Racemic 7-oxabicyclo[2.2.1]heptane-5-exo-iodo-6-endo-hydroxy-2-endo-carboxylic acid-y-lactone

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Title Racemic 7-oxabicyclo[2.2.1]heptane-5-exo-iodo-6-endo-hydroxy-2-endo-carboxylic acid-y-lactone
Author Smith, Graham; Bott, Raymond C.; Jenkins, Ian Douglas; Wermuth, Urs
Journal Name ACTA Crystallographica Section E - Structure Reports Online
Year Published 2001
Place of publication Denmark
Publisher Blackwell Munksgaard
Abstract The crystal structure of the -lactone of racemic 7-oxabicyclo[2.2.1]heptane-5-exo-iodo-6-endo-hydroxy-2-endo-carboxylic acid has confirmed the position of the lactone bridge as 2-6 and the exo-iodo substituent configuration as previously proposed from chemical and 13C NMR evidence. The iodo substituent is also involved in a short non-bonding intermolecular interaction [IO 3.289 (5) Å] with the non-bridging lactone oxygen giving polymeric chains which link weakly hydrogen-bonded (C-HO) centrosymmetric dimer units.
Peer Reviewed Yes
Published Yes
Publisher URI http://www.blackwell-synergy.com/doi/full/10.1107/S1600536801012661
Alternative URI http://scripts.iucr.org/cgi-bin/paper?S1600536801012661
Copyright Statement Copyright 2001 Blackwell Publishing. The definitive version is available at [www.blackwell-synergy.com.]
Volume 57
Page from 806
Page to 808
ISSN 1600-5368
Date Accessioned 2002-06-11
Date Available 2007-03-14T02:37:03Z
Language en_AU
Subject Chemical Sciences
URI http://hdl.handle.net/10072/3564
Publication Type Journal Articles (Refereed Article)
Publication Type Code c1

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