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dc.contributor.authorLiu, Hongwei
dc.contributor.authorWaclawik, Eric R.
dc.contributor.authorZheng, Zhanfeng
dc.contributor.authorYang, Dongjiang
dc.contributor.authorKe, Xuebin
dc.contributor.authorZhu, Huaiyong
dc.contributor.authorFrost, Ray L.
dc.date.accessioned2017-05-03T14:55:04Z
dc.date.available2017-05-03T14:55:04Z
dc.date.issued2010
dc.date.modified2011-08-12T06:19:52Z
dc.identifier.issn19327447
dc.identifier.doi10.1021/jp103644x
dc.identifier.urihttp://hdl.handle.net/10072/39911
dc.description.abstractSodium and hydrogen titanates fibers and three TiO2 polymorphs (TiO2 (B), anatase, and rutile) were prepared from inorganic titanium compounds by hydrothermal reaction and calcination. The nature and morphologies of the nanofibers with layered structure were investigated by means of X-ray diffraction (XRD) and transmission electron microscopy (TEM). It was revealed that the phase transitions between titanates and titania (via proton titanate) could be interpreted systemically by the fundamental building blocks (FBB) model. The reaction also requires interconversion between some corner-linked and edge-linked pairs of TiO6 octahedrons. A generalized relationship of phase transitions between sodium/hydrogen titanates and titania by the wet-chemical process was proposed. A duplex pentagonal prism scheme was implied to summarize all of the phase relationships between titanates and titania.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom11430
dc.relation.ispartofpageto11434
dc.relation.ispartofissue26
dc.relation.ispartofjournalThe Journal of Physical Chemistry C
dc.relation.ispartofvolume114
dc.rights.retentionY
dc.subject.fieldofresearchMacromolecular and Materials Chemistry not elsewhere classified
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchTechnology
dc.subject.fieldofresearchcode030399
dc.subject.fieldofresearchcode03
dc.subject.fieldofresearchcode09
dc.subject.fieldofresearchcode10
dc.titleTEM Investigation and FBB Model Explanation to the Phase Relationships between Titanates and Titanium Dioxides
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyrightSelf-archiving of the author-manuscript version is not yet supported by this journal. Please refer to the journal link for access to the definitive, published version or contact the author[s] for more information.
gro.date.issued2010
gro.hasfulltextNo Full Text
gro.griffith.authorYang, Dongjiang


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