Coordination complexes of silver(I) with tertiary phosphine and related ligands

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Title Coordination complexes of silver(I) with tertiary phosphine and related ligands
Author Meijboom, Reinout; Bowen, Richard J.; Berners-Price, Sue
Journal Name Coordination Chemistry Reviews
Year Published 2009
Place of publication Netherlands
Publisher Elsevier BV
Abstract This paper gives an overview of the structural chemistry of silver(I) coordination complexes. The main discussion is on the halide complexes (F−, Cl−, Br−, I−) but included are also the pseudo-halides (CN−, SCN−) and the classical non-coordinating anions (NO3−, ClO4−, BF4−, PF6−) and oxy-anions (NO3−, H3CCO2−, F3CCO2−, F3CSO3−, etc.). The main focus is on complexes of these silver(I) salts with phosphine ligands, but where relevant the chemistry of other donor ligands is also reviewed. Coordination complexes of silver(I) halides show a rich variation of structural types. The type of structure depends on the stoichiometry of the ligand to silver in the reaction mixture, as well as reaction conditions. Other factors influencing the structure of these complexes include the halide or pseudo-halide ligands used as counterion and the type of solvent.
Peer Reviewed Yes
Published Yes
Alternative URI
Volume 253
Issue Number 3-4
Page from 325
Page to 342
ISSN 0010-8545
Date Accessioned 2011-07-15
Language en_AU
Research Centre Institute for Glycomics
Faculty Faculty of Science, Environment, Engineering and Technology
Subject Classical Physics
Publication Type Journal Articles (Refereed Article)
Publication Type Code c1x

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