Luminescence characteristics and X-ray crystal structure of [Cd(bipy)3][PF6]2 (bipy) = 2,2'-bipyridine)
Author(s)
Kundu, Nabanita
Mandal, Debdas
Chaudhury, Muktimoy
Tiekink, Edward
Griffith University Author(s)
Year published
2005
Metadata
Show full item recordAbstract
The photoluminescence characteristics of the [Cd(bipy)3][PF6]2 complex are reported. A moderately large quantum yield (f) of 1.07 נ10-2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C[BOND]H緷p and C[BOND]H緷F interactions.The photoluminescence characteristics of the [Cd(bipy)3][PF6]2 complex are reported. A moderately large quantum yield (f) of 1.07 נ10-2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C[BOND]H緷p and C[BOND]H緷F interactions.
View less >
View less >
Journal Title
Applied Organometallic Chemistry
Volume
19
Subject
Inorganic Chemistry
Organic Chemistry
Other Chemical Sciences