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dc.contributor.authorSmith, G
dc.contributor.authorWermuth, UD
dc.contributor.authorHealy, PC
dc.contributor.authorWhite, JM
dc.date.accessioned2017-05-03T11:09:30Z
dc.date.available2017-05-03T11:09:30Z
dc.date.issued2003
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH02163
dc.identifier.urihttp://hdl.handle.net/10072/6290
dc.description.abstractThe crystal structures of the proton-transfer compounds of 3,5-dinitrosalicylic acid (dnsa) with a series of common monocyclic heteroaromatic amines (pyridine, 4-cyanopyridine, pyridine-4-carboxylic acid, 2,6-diaminopyridine, and 2-aminopyrimidine) have been determined and the hydrogen-bonding associations in each analyzed. The compounds are the adduct [(C5H6N)+(dnsa)-砨dnsa)] (1), the 1 : 1 salts [(C6H5N2)+(dnsa)-] (2), [(C6H6NO2)+(dnsa)-] (3), [(C5H8N3)+(dnsa)-] (4), and the 2 : 2 ethanol hemi-solvate [2(C4H6N3)+粨dnsa)-砰.5(EtOH)] (5). With all compounds, protonation of the hetero-nitrogen atom occurs with subsequent hydrogen bonding to the oxygen atoms of the functional groups of the dnsa anions, resulting in the formation of relatively simple linear or chain polymer associations. Compound (1) represents a rare example of other than a 1 : 1 association, and the first example of a 2 : 1 (dnsa/amine) type, with the unusual presence of an additional adduct molecule of dnsa in the structure.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeAustralia
dc.relation.ispartofpagefrom707
dc.relation.ispartofpageto713
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume56
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleStructure-Making with 3,5-Dinitrosalicylic Acid. II. The Proton-Transfer compounds of 3,5-Dinitrosalicylic Acid with the Monocyclic Heteroaromatic Amines
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:29:39Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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