Boronate derivatives of bioactive amines: potential neutral receptors for anionic oligosaccharides.

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Title Boronate derivatives of bioactive amines: potential neutral receptors for anionic oligosaccharides.
Author Charles W. Gray, Jr.; Walker, Brian T.; Foley, Robin A.; Houston, Todd Ashley
Journal Name Tetrahedron Letters
Year Published 2003
Place of publication United Kingdom
Publisher Pergamon
Abstract Oligomeric δ-aminoboronates were synthesized via reductive amination of o-formylbenzene boronic acid with several polymines. The process entails the direct addition of o-formylbenzene boronic acid to the polyamine in methanol at room temperature followed by reduction of the resulting imine with NaBH4. Di-, tri-, and tetrameric δ-aminoboronates have been prepared in this manner and these are anticipated to have enhanced affinities for certain oligosaccharides. A novel templating method for the synthesis of these compounds is also described.
Peer Reviewed Yes
Published Yes
Alternative URI http://dx.doi.org/10.1016/S0040-4039(03)00616-6
Volume 44
Page from 3309
Page to 3312
ISSN 0040-4039
Date Accessioned 2004-03-27
Date Available 2015-05-11T00:49:53Z
Language en_US
Research Centre Institute for Glycomics
Faculty Faculty of Science
Subject PRE2009-Organic Chemical Synthesis
URI http://hdl.handle.net/10072/6311
Publication Type Journal Articles (Refereed Article)
Publication Type Code c1

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