The Preparation and Crystal Structure of Ammonium Bismuth(III) Thiosalicylate Dihydrate
Author(s)
Sagatys, DS
Smith, G
Bott, RC
Healy, PC
Griffith University Author(s)
Year published
2003
Metadata
Show full item recordAbstract
The bismuth(III) complex of thiosalicylic acid (2-mercaptobenzoic acid; H2L), ammonium tris(2-mercaptobenzoato-O,S) bismuth(III) dihydrate, {(NH4)3[Bi(L)3]粠H2O}, has been prepared and its crystal structure determined. The distorted octahedral tris-bidentate complex unit has pseudo-C3 symmetry with the facially related thiolate sulfur donors providing a regular facial cap to the octahedron (Bi-S 2.595, 2.596, 2.596(5) ũ with the Bi-O(carboxylate) distances less regular (2.715, 2.741, 2.785(15) ũ. The network polymeric structure is stabilized by hydrogen-bonding associations through both the ammonium counter ions and the lattice ...
View more >The bismuth(III) complex of thiosalicylic acid (2-mercaptobenzoic acid; H2L), ammonium tris(2-mercaptobenzoato-O,S) bismuth(III) dihydrate, {(NH4)3[Bi(L)3]粠H2O}, has been prepared and its crystal structure determined. The distorted octahedral tris-bidentate complex unit has pseudo-C3 symmetry with the facially related thiolate sulfur donors providing a regular facial cap to the octahedron (Bi-S 2.595, 2.596, 2.596(5) ũ with the Bi-O(carboxylate) distances less regular (2.715, 2.741, 2.785(15) ũ. The network polymeric structure is stabilized by hydrogen-bonding associations through both the ammonium counter ions and the lattice water molecules.
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View more >The bismuth(III) complex of thiosalicylic acid (2-mercaptobenzoic acid; H2L), ammonium tris(2-mercaptobenzoato-O,S) bismuth(III) dihydrate, {(NH4)3[Bi(L)3]粠H2O}, has been prepared and its crystal structure determined. The distorted octahedral tris-bidentate complex unit has pseudo-C3 symmetry with the facially related thiolate sulfur donors providing a regular facial cap to the octahedron (Bi-S 2.595, 2.596, 2.596(5) ũ with the Bi-O(carboxylate) distances less regular (2.715, 2.741, 2.785(15) ũ. The network polymeric structure is stabilized by hydrogen-bonding associations through both the ammonium counter ions and the lattice water molecules.
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Journal Title
Australian Journal of Chemistry
Volume
56
Issue
9
Subject
Chemical sciences